Herbicide
专利摘要:
New and valuable diurethanes having a good herbicidal action, herbicides containing these compounds, and a process for controlling the growth of unwanted plants with these compounds. 公开号:SU735151A3 申请号:SU782568150 申请日:1978-01-24 公开日:1980-05-15 发明作者:Ширмер Ульрих;Рор Вольфганг;Вюрцер Бруно;Фетт Курт 申请人:Басф Аг (Фирма); IPC主号:
专利说明:
. . one . The invention relates to chemical plant protection agents, specifically to a herbicidal agent based on diurethane derivatives. A herbicidal agent based on 2- & pure-butyl-4, b-dinitrophenrel 1 is known. The closest in chemical structure to the invention is a herbicide based on 1 -methyl- 3- (s-3-methylphenylcarbamoyloxy) -phenyl-carbam 12. However, these herbicides around f give insufficient activity at low concentrations. obtaining new herbicidal agents possessing their own high herbicidal activity. This goal is achieved by using compounds of the general formula as diurethane derivatives (I "OCzHj de R - hydrogen or normal alkyl; secondary or tertiary butyl; tertiary amyl; allyl; prop argyl; 1-methylpropargyl chloroisopropyl; chlorine-glr &t-butyl; 1-chloromethyl-2-methoxy t. 2, b-dimethyl- and 3,5-dimethylcyclohexyyl; 1-methyl cyclopentyl; norbornyl; phenyl; 2-ethyl, 2-isopropyl, 3-methyl-, 3-etyl-j 4-fluoro-4-chloro , 4-methyl-, 4-isopropyl-, 2-3-dimethyl-, 2,5-dimethyl-, 2,6-dimethyl-, 3,4-, tetramethyl-, 3,5-diethyl-, 2-methyl -5-isopropyl-, 3-methyl-4-chloro, 2-methyl-6-isopropyl- and 3-methyl g 5-ethyl-phenyl; benzyl; or, the radical form / LY (II). , GTG MN-BOO 3 methyl; ethyl; isopropyl; tertiary butyl, allyl, propargyl, or phenyl; Chestye 0.1-95 wt.%. measures. To a solution of parts of a complex 4-chlorophenyl 3-aminophenyl) -carbamic 125 parts by weight tetrahydrofuran Table. 14 gives the herbicide of the compound of the formula jT-dOOF × YAN-COOKD when processing before or after the greenhouse; Table 15 shows the selection of the effect of the compound of the formula O RI after the shoot in the greenhouse. In Table 1b, the selection of a compound of the formula O RI Ej-0- (JN NdO-Bj with weeds in cultivated plants upon treatment after germination in t is given. Table 17 gives a selective outside compound of the formula I jf Bg-O-CJ-N seedling treatment in a teppice. Table 18 gives a selective effect of a compound of the formula .. BUT I G -NCO-RJ with weeds in cultivated plants when processed after a shoot in warming Table 19 gives the effect of urethane formulas R-O-C- and l Weed control in wheat when processed after emergence in warming Table 20 gives a herbicidal action of diurethanes of the formula O RI .r-tch 735151 Continued tabl, 1 ten T a face 2 (known) T-face 3 Table 4 il 735151 1L about g ate oh oh oh oh 1L 00 1L about oh oh about (Tl in w and tTi 00 oh oh PTS about about (N 12 N 00 1L about about oh oh Oh oh l about Ltd about 1L oh oh about oh oh (L o o oh oh (T o oh oh 1L 1L about 1L about 9i o d o w o oh oh about oh oh oh oh oh oh oh about Gel s oh oh oh oh in in about go P (-o ate o (n oh oh about oh oh in 00 00 o o o oh oh 1L oh oh Ш 1Л (N g r in in about in oh oh oh oh MS O) tn in oh oh about oh oh CN (N um 1L LO oh oh oh oh n r oh oh I oh oh oh oh h- in N (N (N (N about 00 I o I o rn 1-N 1G o w o about -( he n (S tN Lfi o och ate oh oh oh oh g-1 1L oh oh 00 1Л (П 1L SP about about ABOUT) with about about (P go about (N) m H Ш s 0) 0 e --X -V ---., - 7 Table 13 3.0. 100 . 33 3.0 21 100 3.0 80 thirty 3.0 80 31 26 3.0 80 CH 3 3,0 80 28 3.0 80 80 3.0 27 37 3.0 100 15 Table 14 95 100 100 10 95 85 80 o 40 Oh oh 40 20 -, Te ::: -ag4 X ---: M- aag5l About 80 65 75 85 o 80 95 80 80 80 80 40 - 80 20 80 100 50 90 40 80 , YH5 SJ; bne Table 15 80 100 lod 85 ten Hjd Table 19 - (JH sn. Jngs11, -snsn, with sn. -s - sn 3 -sn -Sn -dHj -dH -Sn --CHj -sn -engb - 100 100 100 10 20 100 100 100 95,100 99 T a b l and c a 20 3.0 100 sn. 3.0 100. sn. 3.0 100 sn. 3.0 .100 Snd 3.0 100 sn
权利要求:
Claims (1) [1] Continued tabl, 20 Setaria viridis Set. Setaria faberii. Sinapis Sinap aiba. SoEanum nigrum Spergu a arvensis Sperg arv. Ste fcaria media Stef, med, ThCaspl arvense The arsense Triticum aestlvum Triti aest. Xanthium pensylvanicmn Xanth pens. Zea mays AbutiBon theophrasti Chenopodium guinea Datura stramonium Dat. stram Euphorbia genicuCata Euph. gen, Lamium amptexicau e Lamiura purpureum Lam. purp. Nicandra physaCodes Nican phys. Oryza sativa Sorghum bico & or Sorgh Thus, the proposed activities have a high herbicide activity at low ends. Formula of the invention. The herbicidal agent containing the active principle on the basis of spontaneous diurethane, as well as auxiliary components from the number of liquid respiratory carriers, differing in that, for the purpose of higher herbicidal activity, it is a product of diurethane derivatives of the compound formula (I) .l4-600mj KH-dooBa hydrogen or C.-C is normal alkyl; pem-butyl; fetneip-b5 {thyl, amyl, allyl, propargyl, 1-methyl-propargyl, chloroisopropyl, k chloro-rnpft-butyl, 1-chloromegnyl-2-methoxyethyl, cycloalkyl Cg-Cg, 2-methyl-, 4-methyl- , 4-tr-butyl-, 2,6-dimethyl- and 3,5-dimethylcyclohexyl, 1-methylcyclopentyl, norbornyl, phenyl, 2-ethyl, 2-isopropyl-, 3-meGIL-, 3-ethyl, 4- fluorine-, 4-: chloro-, 4-methyl-, 4-isopropyl, 2.3 dimethyl-, 2,5-dimethyl-, 2,6-limethyl-, 3,4-tetramethyl-, 3,5- diethyl-, 2-methyl-5-isopropyl-, 3-methyl-4-HLOR-, 2-methyl-6-isopropyl- and 3-methyl-3-atylphenyl; benzyl or a radical of formula (II) is methyl, ethyl, isopropyl, pethyl, propargyl, or phenyl, keeping the active principle e; 0.1-95 wt.%. information sources, into account when examining US Patent No. 2192197, 22, published. 05.03.75, Switzerland en. 48758U, N Э / 20, published. 31.05.70).
类似技术:
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同族专利:
公开号 | 公开日 DE2703838A1|1978-08-10| DK43878A|1978-08-01| IT1105156B|1985-10-28| ZA78499B|1979-02-28| BR7800538A|1978-09-12| FR2378752B1|1985-02-01| US4227007A|1980-10-07| AU3167077A|1979-06-21| HU178435B|1982-05-28| FR2378752A1|1978-08-25| SE7801097L|1978-08-01| CS196228B2|1980-03-31| NL7801011A|1978-08-02| AT358319B|1980-09-10| JPS5395941A|1978-08-22| GB1596224A|1981-08-19| US4282369A|1981-08-04| ATA63078A|1980-01-15| IT7847839D0|1978-01-30| DD134717A5|1979-03-21| PL105603B1|1979-10-31| AR222632A1|1981-06-15| PL204307A1|1978-11-06| CH635068A5|1983-03-15| AU514853B2|1981-03-05| BE863297A|1978-07-25| IL53643D0|1978-03-10| IL53643A|1982-03-31|
引用文献:
公开号 | 申请日 | 公开日 | 申请人 | 专利标题 US3142699A|1958-04-24|1964-07-28|Bayer Ag|Urethane compounds and process therefor| US3036112A|1959-09-15|1962-05-22|Union Carbide Corp|Bis phenylenedicarbamates| US3297745A|1962-04-05|1967-01-10|Robertson Co H H|Ethylenically unsaturated di-and tetra-urethane monomers| CH436207A|1965-03-02|1967-11-15|Ciba Geigy|Process for the antimicrobial finishing and protection of textiles against harmful microorganisms| US3901936A|1966-10-15|1975-08-26|Schering Ag|Process for the preparation of n-carbamoyloxyphenyl carbamates| US3632530A|1967-03-04|1972-01-04|Yokohama Rubber Co Ltd|Process for decomposition of a polyurethane resin| US3979202A|1970-05-26|1976-09-07|Monsanto Company|Meta-bifunctional benzenes and herbicidal compositions| BE756285A|1969-09-17|1971-03-17|Hoechst Ag|FLUORINE POLYOXETHYLATION PRODUCTS THAT CAN BE USED FOR TEXTILE APPRETATION| DE2043086A1|1970-08-31|1972-03-30|Henkel & Cie GmbH, 4000 Dusseldorf|Low-foaming washing, cleaning and softening agent| US3867426A|1970-10-02|1975-02-18|Monsanto Co|Herbicidal meta-bifunctional benzenes| DE2108975C3|1971-02-16|1979-12-20|Schering Ag, 1000 Berlin Und 4619 Bergkamen|N-acyl diurethanes and herbicidal agents containing them| DE2121957C3|1971-04-27|1979-11-29|Schering Ag, 1000 Berlin Und 4619 Bergkamen|Diurethanes and herbicidal compositions containing them| US3923870A|1973-07-11|1975-12-02|Troy Chemical Corp|Urethanes of 1-halogen substituted alkynes| US4061864A|1973-10-23|1977-12-06|W. R. Grace & Co.|Thiol containing compounds and their preparation| DE2451116A1|1973-11-06|1975-05-07|Sandoz Ag|FLAME RESISTANT COMPOUNDS|DE2846625A1|1978-10-26|1980-05-08|Basf Ag|M-ANILIDURETHANE| OA07768A|1983-05-12|1985-08-30|Sumitomo Chemical Co|Derivatives of fungicidal anillins.| JPS6041312A|1983-08-16|1985-03-05|Tdk Corp|Circuit element| US4833265A|1987-11-02|1989-05-23|Texas Explosives Co Inc|DATB and its bis-urethan| JP2003508512A|1999-09-08|2003-03-04|ギルフォードファーマシュウティカルズインコーポレイテッド|Non-peptidic cyclophilin binding compounds and their uses| MXPA03006666A|2001-01-25|2004-05-31|Guilford Pharm Inc|Trisubstituted carbocyclic cyclophilin binding compounds and their use.| JP5468289B2|2008-04-18|2014-04-09|石原産業株式会社|Method for producing pyrimidine compounds| US9134093B2|2012-08-17|2015-09-15|Vista Outdoor Operations Llc|Holster| CN105175707B|2015-10-23|2017-08-08|西安近代化学研究所|A kind of end alkynyl radical curing agent and preparation method thereof|
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申请号 | 申请日 | 专利标题 DE19772703838|DE2703838A1|1977-01-31|1977-01-31|DIURETHANE| 相关专利
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